When stamps are “cancelled to order”, as in the card that you show, they cannot be postally used years later - so to use in Postcrossing you would have to put them in an envelope and pay the current postage rate.
Yes you would need to add additional postage, as the stamp(s) have been cancelled, same applies to UK made maxicards, the stamp on the front which has been cancelled with a postmark cannot be used for forward postage of the card.